通过连接一个三角棱柱金属簇和一个八面体有机配体,合成了两个非互穿同构且具有nia拓扑结构的金属有机骨架材料,阳离子型JUC-101和阴离子型 JUC-102。JUC-101具有3742 m2/g的BET表面积,在30atm和77 K下能吸附4.18 wt%的氢气。JUC-102能吸收阳离子型染料分子,并能在离子作用下释放它们。
Highly porous and robust ionic MOFs with nia topology constructed by connecting an octahedral ligand and a trigonal prismatic metal cluster. Jiangtao Jia, Fuxing Sun, Tsolmon Borjigin, Hao Ren,Tingting Zhang, Zheng Bian, Lianxun Gao and Guangshan Zhu. Chem. Commun. DOI: 10.1039/C2CC32347H
(聚酰亚胺课题组)